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Transport characteristics of a 134 m thick Opalinus Clay formation in southern Germany obtained from its porewater noble gas profile

Clay-rich formations are internationally considered as ideal seals for underground disposal of radioactive waste [1, 2]. In the context of site exploration programs transport characteristics must - among other information – be locally quantified [3].

Here we present noble gas profiles from Hondingen, southern Germany [4], an area already disqualified as a siting region due to the shallow depth of the Opalinus Clay formation and an active fault zone. The sampling procedure generally followed guidelines for drill core sampling of the recent Nagra drilling campaign [5], refining procedures originally developed elsewhere [6 - 10].

We compare our data with analytical solutions [11] and numerical simulation results [12]. The 4He concentration profile has reached steady state. Within the clay barrier, the transport is diffusion dominated with the minimum porewater residence time calculating to some million years.

[1] M. J. Hendry et al. (2015) Geofluids 15(3) [2] Clay Club Catalogue (2022) NEA, OECD [3] A. Bath, et al. (2023) Appl. Geochem. 159 [4] K. Leu et al. (2023) J. Appl. Region. Geol. [5] D. Rufer and M. Stockhecke (2021) NAB 19-13(1) NAGRA [6] J. Lippmann et al., (1997) IAEA-SM-349/36; [7] K. Osenbrueck, et al. (1998) GCA 62(18) [8] A. P. Ruebel et al. (2002) GCA 66(8) [9] M. Mazurek et al. (2011) Appl. Geochem. 26(7) [10] D. Rufer, et al. (2017) Proc. Earth Planet. Sci., 17, [11] J. N. Andrews (1985) Chem. Geol., 49 [12] D. L. Parkhurst and C. A. J. Appelo (2013) Techniques and Methods, 6(A43), USGS, USA

Details

Author
Johanna Lippmann-Pipke1, Samuel Niedermann2, Karsten Osenbrück1, Hua Shao1, Robert Biskop1, Jana Gerowski1, Daniel Rufer3, Thomas Mann1
Institutionen
1Federal Institute for Geosciences and Natural Resources (BGR), Hannover, Germany; 2Helmholtz Centre Potsdam-GFZ German Research Centre for Geosciences, Potsdam, Germany; 3RWI, Institute of Geological Sciences, University of Bern, Switzerland
Veranstaltung
GeoSaxonia 2024
Datum
2024
DOI
10.48380/cnk3-ng14
Geolocation
Southern Germany