The Rhenohercynian back-arc basin hosts a Lower Carboniferous chert-shale succession that documents variable radiolarian productivity, subareal volcanism and pelagic background sedimentation. To assess the potential of radiolarian cherts to record paleo-productivity and/or oceanic Si concentrations, we investigate silicon isotope ratios (δ30Si) of radiolarian shells, their secondary fills and the matrix in which they are embedded by fs-Laser ablation-MC-ICP-MS. We discuss causes of variations in δ30Si among the analyzed compartments that either point to isotope fractionation during early silicification of the sediments or the presence of two silica sources.